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The Australian National University
Nanotube Research
Research School of Physical Sciences and Engineering
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ball milling

 

High-Energy Ball Milling

 

High-energy ball milling can induce structural changes and chemical reactions at room temperature.  The milling process embraces a complex mixture of fracturing, grinding, high-speed plastic deformation, cold welding, thermal shock, intimate mixing, etc.  Because the structural changes and chemical reactions are realized by mechanical energy rather than thermal energy, reactions are possible at low temperatures and so are non-equilibrium in nature.  High-energy ball milling has produced a large range of nanoscaled materials, including nanocrystalline materials, nanoparticles and nanocomposites during the last decades.  Nanotubes, nanowires and nanorods have also been synthesized using high-energy ball milling in our group.  In addition, the controlled ball milling technique has a large range applications in processing nanomaterials. For example, in the case of nanotubes the ball milling can be used for the following purposes:

•   Scissors in cutting long nanotubes/wires to a short length

•   Opening of caped nanotubes

•   Enhancing functionalization of nanotubes with small molecules

•   Improving hydrogen storage in nanotubes

•   Preparing fine catalyst particles

•   Inducing structural changes/modification by creating active sites on the surface

   

Three different types of milling devices are used at the Australian National University: high-energy rolling steel mill, vibrating ceramic mill and a large-sized planetary ball mill. Detailed information can be found in relevant publications.

 

Rolling ball mill

 

 

Planetary ball mill

 

Vibrating ball mill

 

Ball milling references

  1. "Mechanical Alloying and Milling" C. Suryanarayana, Marcel Dekker, New York 2004
    Book review by Ying Chen, Advanced Materials, 2005, 17, 2893-2894
  2. "Mechnanochemistry and mechanical activation of solids", V.V. BoldyrevRussian Chemical Review, 2006, 75(3) 177-189
  3. "Synthesis of boron nitride nanotubes using ball milling and annealing method "
    Y. Chen, J.S. Williams, in "Nanoengineering of Structural, Functional and Smart Materials". Ed. M.J. Schultz,et al, CRC Press LLC, 2005, p. 169-195